Background
G. L. Leclanché
Dry Cell
No. 6
Gonda - Self Winding Clock Co
Gravity Battery
Battery Charging, see:
Battery
Chargers, Patents
Sodium-Sulfur
Battery
Liquid Metal
Battery
Battery Testing
Other Patents
Lead Acid Batteries
Cylindrical Lead Acid
Battery Makers
Background
This page was started when I
noticed
that a 4 pack of Energizer Alkaline "D" cell batteries has a
large
number of patent numbers. After reading them it was
clear that
when Mercury was banned from batteries sold in the U.S. it not
only
effected "Mercury" batteries but also Alkaline batteries since
at that
time they used Mercury. In order to eliminate the
Mercury in
Alkaline batteries a lot of inovation was required.
Today's
Alkaline batteries have better performance than the older ones
that
contain Mercury.
G. L. Leclanché Patents
Improvement in a battery using
copper
salts. - not zinc carbon type
64113
Electrical Battery with Primary and Secondary Piles Combined
April 23,
1867
429/224
Uses a zinc plate, manganese
peroxide
electrolyte and carbon rod. <-> Key technology pat.
good till 1884
165452
Galvanic-Battery July
13, 1875
429/164
No porous cup needed with
carbon
electrode - combined carbon & manganese peroxide
234413
Galvanic Battery
November 16,
1880
429/163
429/224
Improvements to the carbon
electrode
and the use of a lid to hold both electrodes and make it
easy to
replace the liquid.
Dry Cell
Class Numbers:
29 Metal Working
144 Woodworking and Feeder or Presser
198 Conveyors, Power Driven
425 Plastic Article or Earthenware Shaping or Trating:
Apparatus
429 Chemistry: Electrical Current Producing Apparatus,
Product, and Process
/82 HAVING SPECIFIED VENTING, FEEDING
OR
CIRCULATION STRUCTURE (OTHER THAN FEEDING OR FILLING FOR
ACTIVATING
DEFERRED ACTION-TYPE BATTERY) .Venting structure ..Separate
ventilating
inlet and exhaust openings
130 CURRENT PRODUCING CELL, ELEMENTS,
SUBCOMBINATIONS AND COMPOSITIONS FOR USE THEREWITH AND
ADJUNCTS .
Separator, retainer or spacer insulating structure (other than
a single
porous flat sheet, or either an impregnated or coated sheet
not having
distinct layers) ..Insulator structure is only spacer of the
rod,
button, strip, or frame type
/134 CURRENT PRODUCING CELL, ELEMENTS,
SUBCOMBINATIONS AND COMPOSITIONS FOR USE THEREWITH AND
ADJUNCTS .
Separator, retainer or spacer insulating structure (other than
a single
porous flat sheet, or either an impregnated or coated sheet
not having
distinct layers) .Having electrode enclosing feature
...Cylindrical
unit cell type, flat unit cell type or porous cup type
....Paste or gel
/172 CURRENT PRODUCING CELL,
ELEMENTS,
SUBCOMBINATIONS AND COMPOSITIONS FOR USE THEREWITH AND
ADJUNCTS .Cell
enclosure structure, e.g., housing, casing, container, cover,
etc.
..Cylindrical unit cell type, e.g., cup container electrode,
tubular
electrode, casing, etc. ...Reactive metallic can, cup or
tubular
electrode ....Having seal .....Mechanical clamping pressure
seal
Dry Cell Patents
364369 Galvanic Battery, V. Francken
(Leclanché Battery Co), Jun 14 1867 - method of making the
carbons using either a process similar to that used for making
carbons
for arc lights or a simpler low temperature process that ends
with high
temperature firing in an oven.
,
1246876 Battery Capping Machine, Conrad Hubert, Nov 20, 1917,
29/623.1
; 144/245.1; 144/250.24; 29/730; 29/790 - replaced hand
operation.
Used to apply the small brass cap to the carbon rod.
1388990 Dry Cell, Winchester Repeating Arms Co., Aug 30, 1921,
429/134 ; 429/172
1398366 Dry Cell, Winchester Repeating Arms Co., Nov 29, 1921,
429/82 ; 429/130; 429/172
1430727 Manufacture of Dry Cells, Winchester Repeating Arms
Co., Oct 3, 1922, 29/623.1
1510835 Machine for Tamping Dry-Cell Cartridges and the Like,
Winchester Repeating Arms Co., Oct 7, 1924, 425/128 ; 141/80
1564951 Manufacture of Dry Cells, Winchester Repeating Arms
Co., Dec 8, 1925, 29/623.2
658428 Carbon Pencil Feeding Mechanism, Winchester Repeating
Arms Co., Feb 7, 1928, 198/400 ; 193/47
National Carbon Co
1205629 Circuit Controller for
Portable Lights, G.F. Hitzelberger, Nov 21 1916, - a two
position flash light switch
1216450 Deplolalrizer for Midget Batteries, Major E. Holmes
(National Carbon Co), Feb 20, 1917, 429/224 ; 423/582
-
1264520 Flashlight Battery, Major E. Holmes (National Carbon
Co), Apr 1918, 362/206
; 200/60; 338/101; 338/71; 429/97 - carbon pile adjustable
resistor
allows controling brightness on cylindrical and tab type
battery
flashlights
2773926 Dry Cell, R.L. Glover (Union Carbide), Dec 11 1956, 429/167
; 429/170; 429/173- sheet metal case all around with plastic
to make leak proof
836480 Dry Battery Cell,
(National Carbon Co), Nov 20, 1906, 429/133 ; 429/178
- tapered for improved performance
838165 Battery Cell (National Carbon Co), Dec 11, 1906, 429/229
-
921186 Dry Battery Posting Machine, (National Carbon Co) May
11, 1909, 228/49.2- for soldering the binding post to
the zinc can
1033228 Dry Battery Cell, (National Carbon Co), Jul 23, 1912,
429/165 ; 429/133; 429/166; 429/178
1027088 Waterproof Battery and Method of Making, May 21, 1912,
429/185 - combines No. 6 cells into a battery
1210577 Apparatus for Lining Dry Cells, (National Carbon Co),
Jan 2, 1917 -
1292254 Electric Battery, N.K. Chaney, (National Carbon Co),
Jan 21 1919, 429/199- preventing zinc corrosion
reducing impurities
1369894 Nut Equipmeting Machine, (National Carbon Co), Mar 1,
1921 ,470/49 ; 470/46; 81/125 - for putting on the
thumb nuts
1773310 Dry Cell Terminal, H.W. Jones (National Carbon
Co), Aug 19, 1930, 439/809 ; 429/121 - will not
loosen if wire is moved
Gonda - Self Winding Clock Co
369769
Galvanic Battery, H.J. Brewer, September 13, 1887, 429/133 -
depolarizer is bag around carbon electrode
380084 Galvanic Battery, H.J. Brewer, March 27, 1888,
429/164 - porous-cup and carbon electrode
432973 Galvanic Battery, H.J. Brewer,
441130 Electric Battery Connection, H.J. Brewer,
451364 Electric Connection
557048 Zinc Support for Batteries
576720
Galvanic Battery, H.J. Brewer, New York, February 9, 1897,
429/164 ; 429/175; 429/186; 439/817 - Zinc bracket
579916
Battery Cover, H.J. Brewer, March 30, 1897, 429/175 - holds
rectangular removable carbon
653763
Electrogalvanic Battery, H.J. Brewer, July 17, 1900, 429/178 ;
204/196.18; 204/196.19; 429/186
seperates the carbon and
depolarizer unlike Leclanché where they are combined
resulting in lower resistance.
653764
"
"
"
",
429/209 ;
429/239 - "
653765
"
"
"
",
429/81 ; 429/209
-
"
660836
Electrogalvanic Battery, H.J. Brewer, October 30, 1900,
429/209 ; 429/239 - simpler way of mounting depolarizer on
carbon
677633 Zinc Element for Galvanic Batteries,
694089 Zinc Element for Primary Batteries,
814825 Battery Zinc
900476
Cover for Electric Batteries, H.J. Brewer, October 6,
1908,
429/164 ; 429/186 - cover slotted to accept different types of
carbons
1026847
Cover for Electric Batteries, H.J. Brewer, May 21, 1912,
429/186 -
molded rubber cover has stiffeners so that in summer the cover
will not
sag
Gravity Battery
715654
Gravity Electric Battery, A.M. Friend, Dec 9, 1902, 429/106
-
Isolates solid particles from moving between electrodes to
improve
shelf life
712668
Gravity Battery, W.N. Gove, Nov 4, 1902, 429/106 - replaces
copper with Babbitt metal for much longer life.
393203
Gravity Battery, L. C. Bartley, Nov 20, 1888, 429/106 - Crow's
foot
electrodes and getter to keep Zinc away from copper extending
life
maybe 10 times.
183201
Gravity Battery, M.W. Parrish,
Oct 10, 1876, 429/208 ; 429/106; 429/229 - Mentions Gravity
Battery as
prior art, but this may be the first time the term is used in
a patent?
142999 Galvanic Batteries, T.A. Edison, Sep 23, 1873,
429/106
39571
Improvement in Galvanic Batteries, Edward Hill, August 18,
1863,
429/106
RE2502 Improvement in Galvanic Batteries, Edward Hill,
Re-Issued March 12, 1867, 429/220 ; 429/229
Sodium-Sulfur Battery
YouTube: CATL's Sodium-Ion
Battery: Better than Lithium? - @2:40 the
Sodium-Sulfur battery is mentioned.
The Ford patent started this chemistry.
3413150
Battery having a molten alkali metal anode and a molten sulfur
cathode, Joseph
T Kummer, Weber
Neill, Ford
Motor Co, App: 1966-09-28, Pub: 2008-02-21 - operates
with liquid (molten) Sodium metal (Wiki)
at about 300 deg C.
Liquid Metal Battery
https://www.ted.com/talks/donald_sadoway_the_missing_link_to_renewable_energy
https://ambri.com/technology/
https://patents.google.com/?assignee=Ambri+Inc&sort=new
WO2021050987A1
Systems and methods for grid scale energy storage, Ambri Inc.,
2020-09-11
Don Sadoway holds many patents on Aluminum refining equipment
and the battery is an outgrowth of that.
20080044725
High-amperage energy storage device and method, Donald
Sadoway, Gerbrand
Ceder, David
Bradwell, MIT,
Priority: 2006-08-15, Pub: 2008-02-21
20110014503
Alkaline earth metal ion (Wiki:
Be, Mg, Ca, Sr, Ba, Ra) battery, David
Bradwell, Donald
R. Sadoway, MIT,
App: 2009-07-20, Pub: 2011-01-20
These batteries make use of liquid (molten) metals that
because of their density form into three layers.
Battery Testing
The method of testing needs to
take into account a number of factors:
- Battery Chemistry
- Capacity of battery under test (Amp hours, Watt hours)
- Temperature of the battery while being tested (effects
voltage & indicates problems)
- Load properties, i.e. resistor, constant current,
switching mode power supply (current increases as batt V.
goes down)
Class Numbers:
320 - Electricity: Battery or Capacitor Charging or
Discharging
324 - Electricity: Measuring or Testing
702
- Data Processing: Measuring, Claibrating or Testing
Carbon Zinc and Alkaline
TS-183 - This is a first generation
tester that applies a resistive load and measures the battery
voltage while loaded.
6823274 Apparatus and method for testing remaining capacity of
a battery, Nov 23, 2004, ZTS,
702/63 ; 320/125;
320/136; 702/64; 702/65; 702/79
uses voltage at end of
resistor load pulse. D515444 Battery Tester -
packaging for the 6823274.
Magnesium & some Military Carbon Zinc
PSM-13
- can be carried on a belt and tests radio batteries,
Vietnam era. Uses high current load to activate
Magnesium batteies.
TS-4403 - Specifically made to test
Batteries for: Modern radios like the
PRC-104,
RT-1439 (
SINCGAARS),
PRC-25 and
PRC-77,
PRC-68 Family.
4725784
Method and apparatus for
determining the state-of-charge of batteries particulary
Lithium batteries, Feb 16, 1988,
324/427 ;
320/149; 320/150; 320/162; 340/636.15
Uses pulse loading and voltages
measured at various times in relation to the load pulse as
well as
temperature correction. Capacity depends on manfuacturer
as well
as model.
Mercury
TS-23 - Tests the BA-1574/U Mercury
battery used in the
SDU-5/E
Emergency Survival Strobe Light and the flash rate of the
strobe.
BT-2 - Tests BA-1568/U as used in the PRC-90 Survival Beacon
Radio and
others, BA-1113/U used on the URC-64 Survival Radio, the K308A
battery used on the
RT-10
Survival Radio, and the BA-1574/U used on the
SDU-5/E Emergency Survival Strobe
Light.
Electric Gas Lighting Co
Battery
393123 Galvanic Battery, F.H. Root Nov. 20 1888, (Root
Electric Gas Lighting Co), 429/89 ; 429/164
431742 Galvanic Battery, C.R. Goodwin (Electric Gas Lighting
Co), July 8 1890, 429/149 ; 429/163 - Sampson No 2
431968 Process of Forming Porous Pots for Voltaic Batteries,
C.R.
Goodwin (Electric Gas Lighting Co), July 8 1890, 264/29.1 ;
106/122;
201/21; 264/29.4; 429/176
568007 Electric Battery, H.C. Thompson (Electric Gas Lighting
Co), Sep 22, 1896, 429/164 -
866748 Battery Zinc, H.C. Thompson (Electric Gas Lighting Co),
Sep 24,
1907, 429/229 - cylinder shaped zinc sheets - Sampson No 2
(The EGM Co
Boston)
Annunciator
389423 Electro-Mechanical Gong - combines electromagnet &
clock mainspring
435440 Automatic Electric Annunciator - not EGL Co - each new
call resets prior indication
463001 Electric Annunciator - movement of poison bottles
473121 Electric Annunciator - setback base is Wood NOT iron,
why?
513956 Annunciator - single coil electromagnets ?magnetic
circuit?
521046 Electric Annunciator - coil spring a plunger in EM
525874 Electric Annunciator - reset buttom at bottom
529144 Automatic Set-Back Annunciator - extra electromagnets
used to reset pointers
542664 Electric Annunciator - basic single coil solenoid
?magnetic path?
545069 Electric Annunciator - hinged drop down flag goog
looking magnetic path
573723 Electric Floor-Push - used under dining table to trip
Annunciator in kitchen
Electric Gas-Lighting Apparatus
260804 Electric Gas-Lighting Apparatus
260805 Electric Gas-Lighting Apparatus
375118 Electric Gas-Lighting Apparatus
400795 Spark-Coil
444896 Automatic Electric Igniting Device
644143 Electric Gas-Lighting Candle Burner
Other Patents
49824 Improvement in Galvanic Batteries, J. Blackie, Sep 5,
1865, 429/164
113864 Improved Thermo Electric Pair Moses G. Farmer, Apr 18,
1871, 136/200 ; 136/225 - German Silver and Antiminy-Zinc
300176 Galvanic Element, W. Wenzel, Jun 10, 1884,
304764
Dry Pile September 9,
1884 J.
A. Thiébaut
429/166;
429/224
Replaced the zinc rod with a
zinc can
and combined the manganese peroxide electrolyte with potash
and
gypsum. Looks very similar to a No. 6 battery. It's a
"Dry cell"
battery, i.e. no liquid.
315937 Electric Battery, A. Haid (Excelsior Batt Co), Apr 14,
1885, 429/149 - pocket sized
346207 Galvanic Battery, W.W. Le Grande, Jul 27, 1886, 429/219
; 429/230
364639
Galvanic Battery April
7, 1887 V. Francken & E. Bender assigned to the Leclanché
Battery Co. of N.Y.
Method for making the carbon
cathode
rods.
429/224;
429/220;
429/228; 429/232
373064
Galvanic Battery May
20, 1887 C. Gassner Jr. 429/201; 429/134
The zinc can with a carbon
manganese
central rod is filled with a mixture of:
- Oxide of zinc 1 part by weight
- Sal Ammoniac (ammonium chloride)1 part by weight
- plaster* (plaster of Paris?) 2 parts by weight
- zinc chloride 1 part by weight
- water 2 parts by weight
*Hydrated calcium sulfate makes gypsum. When gypsum is
dehydrated, it makes Plaster of
Paris.
This results in the common flashlight battery.
38146
Carbon Plate for Galvanic Batteries, C Chester, April 14,
1863, 439/887 ; 429/164
34656
Improvement in Liquids for Exciting Galvanic Batteries, M
Vergenes, March 11, 1862, 429/109 - Mangnese peroxide is used
353757
Voltaic Battery, F Partz, Dec 7, 1886, 429/106 ; 429/109 -
mentions porous pot
400235 Galvanic Battery, E. Liebert & A. Rosenthal, Mar
26, 1889, 429/199 - cuts small capsule w/terminals on ends
425959 Galvanic Battery, L.M.J.C.C. Renard, Apr 15, 1890,
429/200 ; 429/202
567959 - Fuel to Electricity?